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Author Topic: Linnard?s hydrogen on demand system without electricity !  (Read 429366 times)

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #180 on: January 16, 2007, 01:57:09 PM »
Hi nickle989,

Thanks for your input. I would say that if you have an idea of how to design a circuit that uses a load and charges a battery then please post a diagram of your idea. I would be very interested in building a circuit that looks like it might accomplish this. I will take your advice on using a lead-acid battery to be charged, unless you can show a circuit that would do this for a NiMah or NiCad battery. This is what I would really want.

As far as the plating of zinc goes, earlier in this thread Dingus Mungus shows a design that could be used for the replating of the zinc that goes along the lines you suggested: the idea of a connection at the bottom of the cell that would keep the flaked zinc in electrical contact with the system. This is a good idea; but I was hoping to use the electrical circuit to regenerate the zinc often enough so that only a thin layer would be replated at a time, that way it would be less likely to flake off. (That's my theory anyway.)

You should have no problem finding magnesium and silver colloids at health food stores, they are common items.

I tried to balance the system chemically earlier in this thread. I began to hurt the hydrogen production rate, and started to form a precipitate so the cell solubility was altered as well. I would be very interested to see if you can have better results. I am always open to suggestions and I hope you can have a breakthrough. Please post your results here so we can all see.

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #181 on: January 16, 2007, 02:14:43 PM »
Hi Chris,

You are going to laugh but the way I have been weighing out my NaOH is by using a ruler with a round pencil taped to its bottom at the balance point with a dixie cup on each end of the ruler. When resting on a table it is balanced. Here is the trick. An American penny minted before 1982 weighs 3.1 grams (approx). A penny minted in 1982 and afterwards weighs 2.5 grams (approx). So I place 40grams/2.5grams per penny = 16 pennies in one cup and add enough NaOH to the other cup to balance. This is my home scale  :D. I don't have any fancy expensive Mettler balances as home. So I don't think I will be weighing my anode anytime soon.

I think initially I will be using the fuel cell to power a load. I have a small propeller motor I purchased with the fuel cell. I hope to show this running on the hydrogen cell as it is producing gas. In the future I hope to charge up batteries for zinc regeneration. One step at a time though.I also think your idea of using a stainless 316 electrode for zinc regeneration is a great idea to try. Let me know how it goes.

Also, could you tell me what adjustable DC power supply mramos suggested to you? I may be interested in that too.

I have noticed that I will need to order the right size hoses to fit the fuel cell, so results for me will be delayed for a bit. I am sorry, but I didn't know what I would need to hook these things together. I am learning as I go so have patience with me everyone.

Thanks for your interest.
« Last Edit: January 17, 2007, 03:35:34 PM by ResinRat2 »

Dingus Mungus

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #182 on: January 16, 2007, 10:25:20 PM »
Hey... A scale is a scale... LOL! :D

My current power supplies are 12V-2A, 9V-1.5A, and 5.6V-.65mA phone chargers.
http://www.circuitspecialists.com/prod.itml/icOid/8173
With this PSU I should be able to determine the best voltage for Zn reduction.
(my current plating is fragile and loose... too much wattage I think)

I still need some solid zinc rods but I'm ordering from a new supplier this time.
Also I'm picking up some 5-10 mesh Tungsten carbide pellets or ingot. (<surface area)
Thanks for the best wishes, and the same goes to you in your PEM experiments.

I know we're close now,
~Dingus

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #183 on: January 17, 2007, 05:09:51 PM »
Hi Everyone,

Well, there are a few conclusions I have arrived at over the last couple of days, and I must say it is a good thing I was delayed by needing to order hoses for the fuel cell. Even though my fancy glass reactor looks cool and I would love to use it with the fuel cell, I think the design will not work properly in this case. The reason for this is because I have been observing the reaction in the cell and even though it seems just hydrogen is being produced, I can see the gas on the zinc electrode slowly coming off, and gas bubbles also rising off the zinc precipitate on the bottom of the reactor. It is my understanding that oxygen entering the hydrogen side of the fuel cell will damage the cell and eventually cause it to no longer function. This tells me I need a completely new set-up to use a fuel cell with. I need to be sure the hydrogen and oxygen are not mixed. This is not possible in the present glass reactor.

Looking back in this thread, Dingus Mungus posted a cell concept (picture is at the bottom of this post.)

I am thinking of building a reactor off his concept design using clear PVC pipe. This idea will use a separate tube for each electrode so I can be sure the gases do not mix; then only use the pure hydrogen on the fuel cell. As long as the PVC piping is resistant to the NaOH solution, I think it will work. I am not sure of that though. I have not found information that answers this question yet.

So there will be another delay until I build a concept reactor. No sense ruining the fuel cell now just to get some data and pretend like I am accomplishing something.

Thanks for your interest.

kukulcangod

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #184 on: January 17, 2007, 06:18:46 PM »
Nonetheless your effort is apreciated so we don't make a mistake,
 Is probably to early for this question but do you have and idea if the battery will use less energy to regenerate the reaction than to recharge itself?

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #185 on: January 17, 2007, 06:49:41 PM »
Hi K,

At this point there is no way to tell the amount of energy needed to periodically regenerate the zinc electrode. There are a few variables still unknown. How efficient is the fuel cell?  Will it be able to handle all the hydrogen produced without building up pressure? What volume of hydrogen is required to keep the fuel cell at maximum output? Do we need a fuel cell stack? How efficiently can we charge a battery to use for periodic zinc regeneration? What is the minimum time and electrical energy needed to keep the zinc from being depleted? I'm sure there are many other variables to add to these, so there is still a great deal of work that needs to be done.

This is going to take some time to work out, but it sounds like an interesting challenge to me. I really wanted to get the fuel cell going, but I think it needs a bit more development before this will happen.

I emailed the PVC company to get information on NaOH resistance. I need to do this before I buy even one part.

Sorry, but that is all I can think of at this point. Let me know if you have any ideas.

Thanks

Dingus Mungus

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #186 on: January 17, 2007, 09:21:38 PM »
I emailed the PVC company to get information on NaOH resistance. I need to do this before I buy even one part.

http://www.eskimo.com/~ghawk/h-o/chemchrt.htm

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #187 on: January 17, 2007, 09:49:24 PM »
Hi Dingus,

Thanks for the info. The NaOH solution will be at a concentration of 10%. Much lower than the 50% on the chart, but this doesn't look like good news. The company that makes the piping hasn't contacted me back yet. I am interested to hear what they say; but I think I will need to look for alternatives. Maybe even a custom-made piece of glassware.

Oh well, just another problem to analyze and overcome.

Thanks again.

Dingus Mungus

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #188 on: January 18, 2007, 12:57:31 AM »
http://www.usplastic.com/catalog/search.asp?search=Polypropylene&x=3&y=13

Just a link to help shove ya in the right direction...  ;D

There are lots of cheap and easy to work with plastics, but Polypropylene is almost as standard as PVC and it comes in clear. Custom glass reactors are  a long way off in the future. There is still lots to learn! Why waste money on a fancy case?

Glad to hear you're so close to sealing a cell for the first time. Should be a great demo.

BTW is your PEM (H2+O2) or (H2+Air)?

~Dingus

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #189 on: January 18, 2007, 01:54:35 PM »
Hi Chris,

Fuel Cell Specs: (Fuel Cell Eco H2/Air)
80x80x48 mm
180 g. Weight - 16cm2 electrode area
300mW Power
0.4-0.96V Generated voltage.

I wasn't sure how to handle the oxygen generation at this point, so I chose the Air cell. I can always change things later.

I believe I have found a configuration that mimicks your reactor idea. I will post a picture once I get it drawn up. It will use simple laboratory glassware. Not terribly expensive; probably less than $100 .

Dave

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #190 on: January 18, 2007, 05:53:38 PM »
Hi Dingus,

OK, here we go. I did a quick hand-drawing of a concept to mimic your reactor. One bottle has the tungsten electrodes and the other has the zinc. This way the gases can be collected seperately. The solution is joined at the bottom through the aspirator openings and the "T" allows the funnel to drain the water back into the system from the fuel cell. The system is closed except at the funnel opening.

I figure two of these can be joined to use the circuit.

The drawing is crude and it is just a concept at this point. Should be about a hundred bucks. I am ordering the parts probably today or tommorrow.

Dingus Mungus

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #191 on: January 19, 2007, 12:00:28 AM »
Looks damn good!

I'm quite excited to see what you come up with. I think the biggest problem you're going to face is the posibility of pressure building in the h2 half of the cell dropping the water level. Outside of that though the design looks flawless. I think you're going to be quite pleased with the fuel cells performance, its a little less power then a AA battery but it'll reduce zinc or run a small DC motor with no problems. Thanks for keeping us all updated as often as possible.

BTW I bought a car this week so now getting supplies should be a whole lot easier.
 ;)

~Dingus

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #192 on: January 19, 2007, 12:47:03 AM »
Hi Chris,

A representative from Alsco (www.clearpvcpipe.com) contacted me and informed me that their pipe will be able to withstand up to a 50% concentration of NaOH as long as the temperature of the liquid does not reach 140?F. So it should easily be able to handle a 10% concentration of NaOH in water like the experiment requires. This is GOOD NEWS.

So maybe building it out of this material may be a good idea afterall. I think it will be cheaper than the previous apparatus; but I need to find out for sure. If you have time, maybe you could help design the apparatus. The materials and costs are on their website.
my electrodes are 7" high tungsten and 6" high zinc rods. The rest is up in the air. I guess I could even cut the electrodes any length that is needed.

You designed the original concept so maybe you could help design the first prototype? What do you say buddy, it should be a snap for you. I would even be willing to fund the purchase of the materials. Heck I would even be willing to pay for one for you if you want it. This is no joke! I want to see this idea developed. Use that program you used to draw up the original concept and design a Clear PVC model for experimental testing.

Draw something up, make a list of the materials and cost, let's add it up and see what is the better way to go. I'll try and do the same for the one I hand-drew and we'll compare costs. What do you say? Let me know what you think. Unless you want to try something else? Just take a few days and decide, then let me know.

Thanks again,

Dave

P.S. BTW, congrats on the car. Hope you like it.


kukulcangod

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #193 on: January 19, 2007, 01:42:22 AM »

Thanks RR
That gets that out of my sweating system ???

One thing I do remember : in the link to griffin's company it says that a system is due for the market, and shows a small translucent like battery powering a small fan so yes somehow is going to work.

"Are you pondering what I'm pondering Pinky?"

ResinRat2

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Re: Linnard?s hydrogen on demand system without electricity !
« Reply #194 on: January 19, 2007, 02:01:28 AM »
Hi K,

This is my thinking on the whole idea so you can see where I am coming from.

Based off my previous experiments I find evidence that it won't take very much power to regenerate the zinc in the cell. If you read the thread way back you will see that I believe the circuit required to cycle through the regeneration will not require much power, and the energy needed for the zinc regeneration will easily be obtained by the fuel cell. The trouble is we were never able to perform a long term test of this idea. This is because we had no apparatus with an automatic switching system that would cycle through the circuits over a period of weeks. I cannot physically sit at a chair and keep switching circuits every 15-20 seconds for days on end; and unless this is done we will never see if this can be overunity or not.

So in order to test the overunity of the system we first need to build an apparatus to test, then we need the circuit to switch. The drawings here depict an apparatus. Once that is built and tested to work then the circuit has to be built and tested. The circuit is now under construction by mramos. Once he finishes it, and the apparatus is built, then the long term testing can begin. I mean over a period of several WEEKS in constant operation.

That is the goal for now. Because of the catalysts in this system it is unlike any other electrolysis that has been performed before. The catalysts lower the activation energy required to perform the electrolysis. That is why it is low voltage, and that is why it has the potential to be overunity. Hydrogen has a high energy potential, and because of this energy in a gaseous state, it can be utilized by the fuel cell to produce electricity. Far more efficiently than by burning it. The added bonus is that all the other parts of the hydrogen cell will then be recycled and regenerated.

I believe this has potential for these reasons; and that is why I am willing to fund and put in effort on this project. This is for the world to see, not just us here in this forum. So now that we all are clear on how I feel about this project, let's just all get on with our work and try and better the world for the future and the future of our families.