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Author Topic: KARPEN PILE  (Read 156189 times)

Offline profitis

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Re: KARPEN PILE
« Reply #540 on: August 20, 2014, 06:32:47 PM »
Intercatalyst spillover/nernst diffusion potentials pretty much the same thing manifesting pomodoro.let's say that your onto something with strict concentration cell theory and say that it is not violent spillover for example in the silver/palladium variety,then what we should actually be doing is allowing partial exposure of the silver cathode to hydrogen atmosphere within the device and upright position to allow for maximum upward electromigration of gas against depth-pressure after each discharge burst?? It might work.it has to work.indeed yor silver wire experiment should have worked for this theory.

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Re: KARPEN PILE
« Reply #540 on: August 20, 2014, 06:32:47 PM »

Offline profitis

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Re: KARPEN PILE
« Reply #541 on: August 20, 2014, 07:46:53 PM »
Here's my own video evidence that fuel cell studies on oxygen spillover from MnO2 onto gold indeed is the case http://yadda.icm.edu.pl/yadda/element/bwmeta1.element.elsevier-f90154b1-a9e9-3857-b425-522244f423a4 .MnO2 is positive in voltage to pure gold foil here in this karpen setup.

Offline profitis

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Re: KARPEN PILE
« Reply #542 on: August 20, 2014, 07:53:56 PM »
Here's a closeup of the above experiment setup.both gold and MnO2 submerged under alkaline electrolyte.gas passage is via diffusion.this experiment will not work under argon,nitrogen.

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Re: KARPEN PILE
« Reply #542 on: August 20, 2014, 07:53:56 PM »
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Offline pomodoro

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Re: KARPEN PILE
« Reply #543 on: August 21, 2014, 06:58:10 AM »
Afer 18 hours of discharging the Iron cell slowly climbed up to -30mV after a few hours. Discharge was very weak. It became anodic.

And now, for the mercury karpen. Check the vid









Offline MarkE

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Re: KARPEN PILE
« Reply #544 on: August 21, 2014, 08:17:02 AM »
So, the Hg ismuch like some of the earlier experiments. 

Is this the end of your testing?

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Re: KARPEN PILE
« Reply #544 on: August 21, 2014, 08:17:02 AM »
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Offline pomodoro

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Re: KARPEN PILE
« Reply #545 on: August 21, 2014, 10:14:30 AM »
Dont know about the Hg till tomorrow.

The difference is that it is far away from the hydrogen up on top.




Offline profitis

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Re: KARPEN PILE
« Reply #546 on: August 21, 2014, 10:17:32 AM »
Wow! I love the speed at which that cell recharges pomodoro.your idea to bury the connecting wire under the mercury is novel.what electrolyte are you using?

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Re: KARPEN PILE
« Reply #546 on: August 21, 2014, 10:17:32 AM »
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Offline profitis

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Re: KARPEN PILE
« Reply #547 on: August 21, 2014, 10:27:00 AM »
I'm frightened of electrolyte seeping up the blue wire-jacket and overrunning the Hg potential but it looks good so far.

Offline profitis

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Re: KARPEN PILE
« Reply #548 on: August 21, 2014, 10:32:39 AM »
Discharging all traces mercury oxides off that mirror surface should happen within minutes

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Re: KARPEN PILE
« Reply #548 on: August 21, 2014, 10:32:39 AM »
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Offline pomodoro

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Re: KARPEN PILE
« Reply #549 on: August 21, 2014, 02:02:01 PM »
Wow! I love the speed at which that cellhttp:// recharges pomodoro.your idea to bury the connecting wire under the mercury is novel.what electrolyte are you using?

Still 1m naoh.

Offline profitis

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Re: KARPEN PILE
« Reply #550 on: August 21, 2014, 02:10:05 PM »
Excellent.NaOH will wet surfaces completely.can you do me a favour quik pomodoro,disengage the short quik and tell me if the voltage still climbs please

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Re: KARPEN PILE
« Reply #550 on: August 21, 2014, 02:10:05 PM »
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Offline pomodoro

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Re: KARPEN PILE
« Reply #551 on: August 21, 2014, 02:41:39 PM »
Sorry I am at home. But 3 hours ago it reached 100 mv in 10 s and 200 in 30s

Offline profitis

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Re: KARPEN PILE
« Reply #552 on: August 21, 2014, 02:44:57 PM »
A good indication.is that blue wire buried all way down under the mercury

Offline pomodoro

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Re: KARPEN PILE
« Reply #553 on: August 21, 2014, 02:59:31 PM »
A good indication.is that blue wire buried all way down under the mercury

Yep. Stripped section is bent at right angle. Plastic of wire practically touches glass base.


Offline profitis

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Re: KARPEN PILE
« Reply #554 on: August 21, 2014, 06:16:39 PM »
Great.guess which electrode is going to be the cathode in this pic.a tiny copper speck is on the carbon.the cell under nitrogen.

 

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